低碳烷烃的选择性氧化
甲烷、乙烷、丙烷等低碳烷烃是页岩气、油田气和炼厂气的主要成分。近期页岩气开采技术的日益成熟为下游化工行业提供了丰富而廉价得原料。开展低碳烷烃的高效催化转化制高附加值化学品具有重要的意义。该研究方向重点开展：1）甲烷选择性直接氧化制甲醛、甲醇等重要的平台分子化合物；2）C2+低碳烷烃选择性氧化制烯烃。着力于发展用于高效高选择性氧化用非金属催化剂（如二维h-BN等），深入探究其作用机理。
近期的主要进展
1、Jinshu Tian, Jiangqiao Tan, Mingliang Xu, Zhaoxia Zhang, Shaolong Wan, Shuai Wang, Jingdong Lin*, Yong Wang*, Highly selective hexagonal boron nitride catalyst in propane oxidative dehydrogenation for olefin production: essential role of oxidative coupling of methyl, Science Advances, 2019, 5, eaav8063, DOI: 10.1126/sciadv.aav8063
|
2、Jinhan Lin, Jinshu Tian, Xiaojie Cheng, Jiangqiao Tan, Shaolong Wan, Jingdong Lin*, Yong Wang*, Propane ammoxidation over MoVTeNb oxide catalyst in a microchannel reactor, AIChE Journal, 2018, 64(11), 4002-4008, DOI: 10.1002/aic.16377
3、Jinshu Tian, Jinhan Lin, Mingliang Xu, Shaolong Wan, Jingdong Lin*, Yong Wang, Hexagonal boron nitride catalyst in a fixed-bed reactor for exothermic propane oxidation dehydrogenation, Chemical Engineering Science, 2018, 186, 142-151. DOI: 10.1016/j.ces.2018.04.029
